Return to balancing half-reactions in basic solution
Here is the half-reaction in basic solution:
MnO4¯ ---> MnO2
Step One: Balance the half-reaction AS IF it were in acid solution.
3e¯ + 4H+ + MnO4¯ ---> MnO2 + 2H2O
Step Two: Convert all H+ to H2O.
3e¯ + 4H2O + MnO4¯ ---> MnO2 + 2H2O + 4OH¯
Step Three: Remove any duplicate molecules or ions.
3e¯ + 2H2O + MnO4¯ ---> MnO2 + 4OH¯